SYNONYMS: All aluminum alloys 1XXX – 8XXX including, aluminum alloys containing lead (2011 & 6262
APPEARANCE AND ODOR: Grey to silver solid, odorless
USES: Primary metal
COMPOSITION / INFORMATION ON INGREDIENTS
NAME |
CAS No. |
LD 50 |
LC 50 |
EC DIRECTIVE Symbol/R phases |
Conc |
|
|
|
|
|
|
Base Metal |
|||||
Aluminum |
7429-90-5 |
unknown |
unknown |
None |
< 80-99.7 |
|
|
Alloying Elements |
|
|
|
Nickel |
7440-02-0 |
9000mg/kg |
unknown |
Xn 40-43 |
< 5% |
Chromium |
7440-47-3 |
unknown |
unknown |
not classified |
<0.5% |
Silicon |
7440-21-3 |
3160mg/kg |
unknown |
None |
< 14% |
Magnesium |
7439-96-4 |
unknown |
unknown |
None |
< 10% |
Copper |
7440-50-8 |
unknown |
unknown |
None |
< 10% |
Tin |
7440-31-5 |
unknown |
unknown |
None |
<2% |
Iron |
7439-89-6 |
unknown |
unknown |
None |
<2% |
Cobalt |
7440-48-4 |
6170mg/kg oral |
|
Xn 42-43 |
<2% |
Zinc |
7440-66-6 |
unknown |
unknown |
None |
<10% |
Manganese |
7439-96-5 |
9000mg/kg oral |
unknown |
None |
<2% |
|
|
|
|
|
|
Leaded Alloys 2011 & 6262 |
|||||
Lead |
7439-92-1 |
unknown |
unknown |
not classified |
<1% |
Note: Aluminum will be comprised of various combinations of the elements shown above, in addition to other alloying elements That may be present in minute quantities. No permissible exposure limits (PEL) or threshold limit values (TLV) exist for them. Values shown are applicable to component elements.
HAZARDS IDENTIFICATION
Dust from grinding welding cutting etc. may present a lead contamination and an explosion hazard
FIRST AID MEASURES
In case of dust exposure:
FIRE FIGHTING MEASURERS
Extinguishing Media: Not a fire hazard unless in particle form. Suspensions of aluminum dust may pose a severe explosion hazard. A potential for explosion exists for a mixture of fine and course particles if at least 15% to 20% of the material is finer than 44 microns (325 mesh). In case of aluminum fires use a “Class D” dry powder fire extinguisher. DO NOT use water or halogenated extinguishing media
Hazardous Combustion Products: Not applicable
ACCIDENTAL RELEASE MEASURES
Recycle: Aluminum in the form of particles may be reactive and its hazardous characteristics should be determined prior to disposal
HANDLING AND STORAGE
Handling Precautions: Because of the risk of explosion, aluminum ingots and scrap metal should be thoroughly dried prior to re-melting. Use standard methods to check metal temperatures before handling
Storage Conditions: Not applicable
EXPOSURE CONTROLS
|
Exposure Limits |
ACGIH TWA STEL |
OSHA (PEL) TWA & Ceiling |
|
Aluminum tot. dust |
15 mg/m3 none |
10 mg/m3 none |
|
-fume,powder |
5mg/m3 none |
5 mg/m3 none |
|
Cobalt metal/dust/ |
0.05 mg/m3 none |
0.1 mg/m3 none |
|
Lead inorg. |
0.15 mg/m3 none |
0.05 mg/m3 none |
|
Silicon (tot. dust) |
10 mg/m3 none |
15 mg.m3 none |
|
-Resp dust |
none none |
5 mg/m3 none |
|
Tin metal & oxide |
2 mg/m3 none |
2 mg/m3 none |
|
Chromium metal |
0.5 mg/m3 none |
1.0 mg/m3 none |
|
Nickel metal |
1.0 mg/m3 none |
1 mg/m3 none |
|
Iron oxide |
none none |
10 mg/m3 none |
|
Copper (fume) |
0.2 mg/m3 none |
0.1 mg/m3 none |
|
- dust |
1.0 mg/m3 none |
1.0 mg/m3 none |
|
Zinc oxide fume |
5 mg/m3 10 mg.m3 |
5 mg/m3 none |
|
Tot. dust |
10 mg/m3 none |
15 mg/m3 none |
|
Manganese (dust) |
5 mg/m3 none |
5 mg/m3 5 mg/m3-ceiling |
|
Fumes |
1 mg/m3 3 mg/m3 |
5 mg/m3 5 mg/m3 |
PHYSICAL AND CHEMICAL PROPERTIES
Ph: N/A Flashpoint: N/A
Boiling point: N/A Auto ignition temp: N/A
Melting Point: >1200C Lower Flammable limit: N/A
Vapor Pressure: N/A Higher flammable limit: N/A
Evaporation rate: N/A Explosive properties: N/A
Relative density (water=1); App. 2 NFPA Fire Code: 0
Water Solubility: N/A Oxidizing properties: N/A
Partition coefficient (n-octanol/water): N/A Odor threshold: N/A
STABILITY AND REACTIVITY
Stable (yes / no): Yes
Conditions and Materials to Avoid: Molten aluminum may explode on contact with water, may also explode when in contact with halogenated acids, halogenated solvents, bromates, iodates or ammonium nitrate. Aluminum particles on contact with copper, lead, or iron oxides can react vigorously with the release of heat if there is a source of ignition or intense heat.
Hazardous Decomposition Products: In the form of particles, aluminum reacts with halogenated acids, water and sodium hydroxide, producing a flammable gas
TOXICOLOGICAL INFORMATION
Routes of Exposure: Inhalation: Yes Ingestion: No
Eye contact: No Skin contact: No Skin Absorption: No
Acute Effects:
In case of dust exposure;
Inhalation: Solid aluminum does not present an inhalation hazard. Aluminum and silicon dusts generated during use are considered nuisance particles. High concentrations of freshly formed fumes of copper, magnesium, manganese, or zinc oxides can produce symptoms of metal fume fever. High concentrations of copper dusts can also cause irritation of the upper respiratory tract.
Skin Contact: Skin contact with hot metal may cause burns
Eye Contact: Aluminum dust may cause eye irritation
Ingestion: N/A
Chronic Effects;
This product may contain lead. The following effects may occur;
Lead compounds bioaccumulate. The most frequent chronic effects are anemia, kidney and central nervous damages. Medical surveillance should be undertaken to prevent high blood lead levels. Inhalation of lead oxide fumes can cause abdominal pains, constipation, headaches, weakness, muscle pains, loss of appetite, nausea and vomiting. Nickel fumes cause severe pneumonitis and/or sensitization. Aluminum fumes generated during welding or melting present low health risk. High concentrations of manganese dust can affect the central nervous system
Medical conditions aggravated by exposure to product: Not determined
ECOLOGICAL INFORMATION
No information available
DISPOSAL CONSIDERATIONS
Recycle if possible. Dispose of waste in accordance with Federal, State or local regulations
TRANSPORTATION INFORMATION
This product is not classified as dangerous under Transportation Regulations, for all road, rail, sea, or air transport (no UN number)
REGULATORY INFORMATION
WHMIS CLASSIFICATION (Canada): D2 Material causing other toxic effects
EEC CLASSIFICATION (Europe): Not classified
|
Warning symbol: |
None |
|
Warning word: |
None |
|
Risk phrases: |
None |
|
Safety phrases: |
None |
USA REGULATIONS
This product contains lead. Any process resulting exposure to more than 0.5 ug/ of metal dust
may result in a daily dose of lead of over 0.5 ug/ day, the dose above which the “California Safe Drinking Water and Toxic Enforcement Act” of 1986 requires notification. Refer to the appropriate regulation notification wording guidelines.
Section 313 Supplier Notification
This product may contain the following toxic chemical (s) subject to the reporting requirements of section 313 of the emergency Planning and community Right to know Act of 1986 (Title III of SARA) and of 40 CFR 372
| Chemical Name | CAS # |
| Manganese | 7439-96-5 |
| Chromium | 7440-47-3 |
| Nickel | 7440-02-0 |
| Copper | 7440-50-8 |
| Cobalt | 7440-48-4 |
| Lead | 7439-92-1 |
OTHER INFORMATION
Abbreviations:
CAS # = Chemical Abstract Service Registry Number; EC = European Community;
LD 50 = Lethal Dose 50%; LC 50 = Lethal Concentrations; LCLo = Lowest published lethal concentration
OSHA = Occupational Health and Safety Act
PEL = Permissible exposure limit
Reason for modification: Standardization according to ISO specifications
DISCLAIMER
NOTE *The information contained in this MSDS is believed to be correct as obtained from sources we believe to be reliable. However, no representations, guarantees or warranties of any kind have been made as to its accuracy, suitability for particular applications, hazards connected with the use of the material or the results to be obtained from the use thereof. The user assumes all risks and liability resulting from any use, processing or handling of any material. Variations in methods, conditions and equipment used to store, handle or process the material and hazards connected with the use of the material are solely the responsibility of the use and remain at its sole discretion. This product may be coated with an oil-based product or some other such type of substance, or rust preventive before shipping and the MSDS sheet is not included with this MSDS sheet.
No chemical analysis has been performed by or for our company with respect to the items listed in this MSDS. Our various suppliers have furnished the data supplied. Compliance with all applicable federal, state and local laws and regulations remains with the responsibility of the user, and the user has the responsibility to provide a safe work place to examine all aspects of its operation and to determine if or where precautions, in addition to those described herein are required. Db